Crystal structure and magnetic properties of the spin crossover complex FeII(ethyl nicotinate)2[AuI(CN)2]2

被引：23
|
作者：
Sugaya, Akihiro [1 ]
Ueno, Shotaro [1 ]
Okabayashi, Jun [2 ]
Kitazawa, Takafumi [1 ,3 ]
机构：
[1] Toho Univ, Fac Sci, Dept Chem, Chiba 2748510, Japan
[2] Univ Tokyo, Res Ctr Spectrochem, Bunkyo Ku, Tokyo 1130033, Japan
[3] Toho Univ, Res Ctr Mat Integrated Properties, Chiba 2748510, Japan
来源：
NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 05期
关键词：
CADMIUM CYANIDE HOST; TRANSITION; FRAMEWORK; PRESSURE; BEHAVIOR; COMPOUND; STATE; 2D; CONVERSION; MECHANISM;
D O I：
10.1039/c3nj01564e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new Fe-II two-step spin crossover (SCO) coordination polymer, Fe-II(ethyl nicotinate)(2)[Au-I(CN)(2)](2) 1, with four-inflection associated with phase transitions, has been synthesized. Complex 1 with large side chain ligands has been found to undergo unbalanced two-step SCO transitions. This phenomenon is associated with aurophilic interactions through the pairing of bilayers and quadruple effects.
引用
收藏
页码：1955 / 1958
页数：4
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