Europium(II) oxyiodide

被引：14

作者：

Liao, W ^{[1
]}

Dronskowski, R ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270103028671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Yellow single crystals of Eu4OI6 were grown from fluxes in Ta ampoules and structurally characterized by X-ray diffraction. Eu4OI6 crystallizes in a hexagonal system and is isotypic with the corresponding chloride and bromide compounds. The O atom and one Eu atom lie on sites with 3m symmetry; the other Eu atom and the two unique I atoms are at sites with m symmetry. The structure is characterized by O-centered tetrahedra of divalent europium cations [Eu-O = 2.391 (15) and 2.416 (5) Angstrom, and mean Eu-Eu = 3.94 Angstrom] and hexagonal channels along [001] filled with iodide anions.

引用

页码：I23 / I24

页数：2

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