Indication of PCDD/F formation through precursor condensation in a full-scale hazardous waste incinerator

被引：31

作者：

Vermeulen, Isabel ^{[1
]}

Van Caneghem, Jo ^{[1
]}

Vandecasteele, Carlo ^{[1
]}

机构：

[1] Univ Louvain, Dept Chem Engn, ProcESS, B-3001 Louvain, Belgium

来源：

JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT | 2014年 / 16卷 / 01期

关键词：

Incineration; PCDD/F; Dioxin; Hazardous waste; Fingerprint; DIBENZO-P-DIOXINS; CHLORINATED HYDROCARBONS; COMBUSTION; DESTRUCTION; CARBON;

D O I：

10.1007/s10163-013-0160-7

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

This paper gives the PCDD/F fingerprint of boiler and fly ash of a full scale hazardous waste incinerator and demonstrates that, when the waste to be incinerated contains high concentrations of PCBs and chlorinated pesticides, heterogeneous precursor condensation is the dominant PCDD/F formation mechanism rather than de novo synthesis. This is in contrast to full-scale municipal solid waste incinerators, where de novo synthesis has been shown to be the dominant PCDD/F formation mechanism. This paper agrees with earlier predictions based on numerous lab scale experiments.

引用

页码：167 / 171

页数：5

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