CRYSTAL STRUCTURE OF TRANS-BIS(TRIFLUOROACETYLACETONATO) COPPER(II)

被引：3
|
作者：
Baidina, I. A. [1 ]
Stabnikov, P. A. [1 ]
Gromilov, S. A. [1 ]
Smolentsev, A. I. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 49卷 / 05期
关键词：
copper; beta-diketonates; single crystal X-ray diffraction; crystal chemistry;
D O I：
10.1007/s10947-008-0164-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Triclinic modification of trans-bis(trifluoroacetylacetonato) copper(II) is studied by single crystal X-ray diffraction (diffractometer X8 APEX BRUKER, MoK(alpha) radiation, T = 173(2) K). The structure is molecular. Square environment of the Cu atom (Cu-O(av) 1.916 angstrom, angle O-Cu-O(av) 93.4 degrees) is completed to a bipyramid by two C gamma atoms of neighboring molecules, Cu...C gamma 3.18 angstrom and 3.23 angstrom.
引用
收藏
页码：957 / 960
页数：4
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