Hydrothermal Synthesis of 1-Butanol from Ethanol Catalyzed with Commercial Cobalt Powder

被引：22

作者：

Zhang, Xianlong ^{[1
]}

Liu, Ziwei ^{[1
]}

Xu, Xingliang ^{[1
]}

Yue, Huijuan ^{[1
]}

Tian, Ge ^{[1
]}

Feng, Shouhua ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130023, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 12期

基金：

中国国家自然科学基金; 高等学校博士学科点专项科研基金;

关键词：

Ethanol; I-Butanol; Cobalt powder; Green chemistry; Hydrothermal synthesis; CARBON-DIOXIDE; N-BUTANOL; CONDENSATION-REACTIONS; BORROWING HYDROGEN; BASIC OXIDES; ALCOHOLS; HYDROXYAPATITE; COPPER;

D O I：

10.1021/sc400245s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We reported a highly efficient conversion of ethanol to 1-butanol under hydrothermal conditions with commercial cobalt (Co) metal powder as a recyclable and inexpensive catalyst. The possible reaction pathways were explored. Moreover, it has been found that sodium bicarbonate is better than sodium hydroxide for the Guerbet reaction because the former led to less corrosion of reaction vessels and blocked the oxidation of the ethanol to acetic acid.

引用

页码：1493 / 1497

页数：5

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