Activity of different zeolite-supported Ni catalysts for methane reforming with carbon dioxide

被引：110

作者：

Luengnaruemitchai, Apanee ^{[1
]}

Kaengsilalai, Athiya ^{[1
]}

机构：

[1] Chulalongkorn Univ, Petr & Petrochem Coll, Bangkok 10330, Thailand

来源：

CHEMICAL ENGINEERING JOURNAL | 2008年 / 144卷 / 01期

关键词：

CH4; CO2; reforming; Ni; Zeolite; Carbon deposition;

D O I：

10.1016/j.cej.2008.05.023

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The catalytic performance of Ni based on various types of zeolites (zeolite A, zeolite X, zeolite Y, and ZSM-5) prepared by incipient wetness impregnation has been investigated for the catalytic carbon dioxide reforming of methane into synthesis gas at 700 degrees C, at atmospheric pressure, and at a CH4/CO2 ratio of 1. It was found that Ni/zeolite Y showed better catalytic performance than the other types of studied zeolites. In addition. the stability of the Ni/zeolite Y was greatly superior to that of the other catalysts. A weight of Ni loading at 7 wt.% showed the best catalytic activity on each zeolite support; however, the 7% Ni catalysts produced a higher amount of coke than that of two other Ni loadings, 3 and 5%. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：96 / 102

页数：7

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