Reductive coupling of carbonyl compounds using silole and germole dianions

被引：7

作者：

Liu, YX ^{[1
]}

Ballweg, D ^{[1
]}

West, R ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Organosilicon Res Ctr, Madison, WI 53706 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 26期

关键词：

Aldehydes - Germanium - Ketones - Negative ions - Reduction - Silicon - Stereochemistry;

D O I：

10.1021/om0106837

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reductive coupling of aryl aldehydes and ketones is induced by silole and germole dianions at -78 °C in THF, and 1,2-diols are obtained as the only or major products.

引用

页码：5769 / 5770

页数：2

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