Reductive coupling of carbonyl compounds using silole and germole dianions

被引：7
|
作者：
Liu, YX [1 ]
Ballweg, D [1 ]
West, R [1 ]
机构：
[1] Univ Wisconsin, Dept Chem, Organosilicon Res Ctr, Madison, WI 53706 USA
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 26期
关键词：
Aldehydes - Germanium - Ketones - Negative ions - Reduction - Silicon - Stereochemistry;
D O I：
10.1021/om0106837
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reductive coupling of aryl aldehydes and ketones is induced by silole and germole dianions at -78 °C in THF, and 1,2-diols are obtained as the only or major products.
引用
收藏
页码：5769 / 5770
页数：2
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