RECENT APPLICATIONS IN ORGANIC SYNTHESIS OF VISIBLE LIGHT PHOTOREDOX CATALYSIS

被引:5
作者
de Almeida, Angelina M. [1 ]
de Almeida, Mauro V. [1 ]
Amarante, Giovanni W. [1 ]
机构
[1] Univ Fed Juiz de Fora, Dept Quim, BR-36036900 Juiz De Fora, MG, Brazil
来源
QUIMICA NOVA | 2015年 / 38卷 / 08期
关键词
photoredox catalysis; visible light; transition metals; organocatalysis; organic synthesis; C-H BONDS; RADICAL-ADDITION; ARTIFICIAL PHOTOSYNTHESIS; COUPLING REACTION; DIRECT ARYLATION; DUAL CATALYSIS; COMPLEXES; PHOTOCATALYSIS; ACID; ORGANOCATALYSIS;
D O I
10.5935/0100-4042.20150121
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the past few years, photoredox catalysis has become a powerful tool in the field of organic synthesis. Using this efficient method, it is possible to excite organic compounds from visible light and attain alternative mechanistic pathways for the formation of chemical bonds, a result which is not obtainable by classical methods. The rapid growth of work in the area of photoredox catalysis is due to its low cost, broad chemical utility protocols, and, especially, its relevancy from the green and sustainable chemistry viewpoints. Thus, this study proposes a brief theoretical discussion of and highlights recent advances in visible-light-induced photoredox catalysis through the analysis of catalytic cycles and intermediates.
引用
收藏
页码:1080 / 1092
页数:13
相关论文
共 76 条
[1]   ORGANOCATALYSIS REACTIONS WITH CHIRAL AMINES. MECHANISTIC ASPECTS AND USE ON ORGANIC SYNTHESIS [J].
Amarante, Giovanni W. ;
Coelho, Fernando .
QUIMICA NOVA, 2009, 32 (02) :469-481
[2]  
Andrews R. S., 2013, ANGEW CHEM INT EDIT, V125, P13107
[3]   Chiral Bronsted Acid-Catalyzed Stereoselective Mannich-Type Reaction of Azlactones with Aldimines [J].
Avila, Eloah P. ;
Justo, Rodrigo M. S. ;
Goncalves, Vanessa P. ;
Pereira, Adriane A. ;
Diniz, Renata ;
Amarante, Giovanni W. .
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (01) :590-594
[4]   Bronsted Acid Catalyzed Highly Diastereoselective Michael-Type Addition of Azlactones to Enones [J].
Avila, Eloah P. ;
de Mello, Amanda C. ;
Diniz, Renata ;
Amarante, Giovanni W. .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (10) :1881-1883
[5]   Recent Advances in Asymmetric Counteranion-directed Catalysis (ACDC) [J].
Avila, Eloah P. ;
Amarante, Giovanni W. .
CHEMCATCHEM, 2012, 4 (11) :1713-1721
[6]  
Basudev S., 2013, J AM CHEM SOC, V135, P5505
[7]   Visible-light-mediated photochemistry: accelerating Ru(bpy)32+-catalyzed reactions in continuous flow [J].
Bou-Hamdan, Farhan R. ;
Seeberger, Peter H. .
CHEMICAL SCIENCE, 2012, 3 (05) :1612-1616
[8]  
Cano-Yelo H., 1984, J. Chem. Soc., V6, P1093
[9]   Tandem cycloisomerization/Suzuki coupling of arylethynyl MIDA boronates [J].
Chan, Julian M. W. ;
Amarante, Giovanni W. ;
Toste, F. Dean .
TETRAHEDRON, 2011, 67 (24) :4306-4312
[10]   Mechanisms and applications of cyclometalated Pt(II) complexes in photoredox catalytic trifluoromethylation [J].
Choi, Won Joon ;
Choi, Sungkyu ;
Ohkubo, Kei ;
Fukuzumi, Shunichi ;
Cho, Eun Jin ;
You, Youngmin .
CHEMICAL SCIENCE, 2015, 6 (02) :1454-1464