Solvent- and catalyst-free regioselective hydrophosphanation of alkenes

被引：62

作者：

Alonso, Francisco ^{[1
,2
]}

Moglie, Yanina ^{[1
,2
]}

Radivoy, Gabriel ^{[3
]}

Yus, Miguel ^{[1
,2
]}

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

[2] Univ Alicante, Inst Sintesis Organ, E-03080 Alicante, Spain

[3] Univ Nacl Sur, Inst Quim Sur INQUISUR CONICET, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 10期

关键词：

CHIRAL PHOSPHORUS LIGANDS; C BOND FORMATION; ASYMMETRIC-SYNTHESIS; P-C; INTRAMOLECULAR HYDROPHOSPHINATION/CYCLIZATION; INTERMOLECULAR HYDROPHOSPHINATION; ACRYLONITRILE HYDROPHOSPHINATION; OLEFIN INSERTION; PHOSPHINE; PHOSPHINOALKENES;

D O I：

10.1039/c2gc35898k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrophosphanation of alkenes, an atom-economy process typically promoted by radicals or metal species, has been shown to take place in the absence of a catalyst, under solvent-free conditions and in a regioselective manner.

引用

页码：2699 / 2702

页数：4

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