Synthesis and reactivity of tricarbonyl (1-methoxycarbonyl-5-phenylpentadienyl)iron(1-+) cation

被引：7
作者：
Chaudhury, S
Donaldson, WA
Bennett, DW
Haworth, DT
Siddiquee, TA
Kloss, JM
机构：
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
[2] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 09期
基金：
美国国家卫生研究院;
关键词：
carbonyl iron complexes; dienyl; nucleophilic attack; crystal structure;
D O I：
10.1016/j.jorganchem.2004.01.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tricarbonyl(1-methoxycarbonyl-5-phenylpentadienyl)iron(1+) hexafluorophosphate (7) was prepared in two steps from tricarbonyl(methyl 6-oxo-2,4-hexadienoate)iron. While addition of carbon and heteroatom nucleophiles to 7 generally occurs at the phenyl-substituted dienyl carbon to afford (2,4-dienoate) iron products, the addition of phthalimide proceeded at C2 to afford a (pentenediyl) iron product (18). Complex 18 was structurally characterized by X-ray diffraction analysis. (C) 2004 Elsevier B.V. All rights reserved.
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页码：1437 / 1443
页数：7
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