Comparison of the UV-Induced Photolysis, Ozonation, and Their Combination at the Same Energy Input Using a Self-Devised Experimental Apparatus

被引:4
作者
Alapi, Tuende [1 ,2 ]
Berecz, Lajos [1 ]
Arany, Eszter [2 ]
Dombi, Andras [2 ]
机构
[1] Univ Szeged, Dept Inorgan & Analyt Chem, H-6701 Szeged, Hungary
[2] Univ Szeged, Inst Chem, Res Grp Environm Chem, H-6720 Szeged, Hungary
关键词
Ozone; Photolysis; UV; VUV; Hydroxyl Radical; Low-Pressure Mercury Vapor Lamp; pH Effect; RATE CONSTANTS; OZONE DECOMPOSITION; WATER; PHENOL; DEGRADATION; RADIATION; RADICALS; PHOTOOXIDATION; NONYLPHENOL; OCTYLPHENOL;
D O I
10.1080/01919512.2013.814481
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The efficiency of the UV photolysis, ozonation and their combination were compared in the decomposition of phenol using a self-devised experimental apparatus running under identical power conditions. The light source was a low-pressure mercury vapor lamp emitting at 185 nm (responsible for the formation of ozone) and 254 nm (responsible for the direct photolysis of ozone and phenol). The effect of flowrate of oxygen or air on the concentration of formed ozone in the gas phase, the effect of dissolved oxygen and pH on the transformation of phenol and formation of intermediates in aqueous solution were also investigated.
引用
收藏
页码:350 / 358
页数:9
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