Na(H2O)[Mn(H2O)2(BP2O8)]: Crystal structure refinement

被引：7

作者：

Yakubovich, O. V. ^{[1
]}

Steele, I. ^{[2
]}

Dimitrova, O. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Geol, Moscow 119992, Russia

[2] Univ Chicago, Chicago, IL 60637 USA

来源：

CRYSTALLOGRAPHY REPORTS | 2009年 / 54卷 / 01期

关键词：

DOT H2O; MONOHYDRATE; BOROPHOSPHATE; DIAQUA; ZINCOBOROPHOSPHATE; DEHYDRATION;

D O I：

10.1134/S1063774509010039

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of synthetic manganese sodium borophosphate hydrate Na(H2O)[Mn(H2O)(2)(BP2O8)] was refined based on X-ray diffraction data. The compound was prepared by soft hydrothermal synthesis in the MnCl2-Na3PO4-B2O3-H2O system. The unit-cell parameters are a= 9.602(1) A..., c= 16.037(3) A..., sp. gr. P6(5)22, Z= 6, D (x) = 2.57 g/cm(3). The water molecules were found to be statistically distributed in the channels of the mixed anionic paraframework consisting of (BO4) and (PO4) tetrahedra and [MnO4(H2O)(2)] octahedra. The hydrogen atoms of the water molecules coordinated to the Mn2+ cations were located and their positional and thermal parameters were refined. The crystal-chemical features of borophosphates of the general formula A (x) M(H2O)(2)(BP2O8)(H2O) are considered.

引用

页码：13 / 18

页数：6

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[41] Crystal structure and spin-trimer magnetism of Rb2.3(H2O)0.8Mn3[B4P6O24(O,OH)2] [J].

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Volkov, Anatoly S. ;

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[42] The solid-state thermal decomposition of Sr3[La(C2O4)3(H2O)2]2•11H2O [J].

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[43] Crystal structure of di-(L-alanine)monophosphite monohydrate [C3O2NH7]2•H3PO3•H2O [J].

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