Synthesis of periodic mesoporous organosilicas with block copolymer templates

被引：106

作者：

Burleigh, MC

Markowitz, MA

Wong, EM

Lin, JS

Gaber, BP

机构：

[1] USN, Res Lab, Lab Mol Interfacial Interact, Ctr Biomol Sci & Engn, Washington, DC 20375 USA

[2] Oak Ridge Natl Lab, Div Solid State, Oak Ridge, TN 37831 USA

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 12期

关键词：

D O I：

10.1021/cm010852d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Large pore periodic mesoporous organosilicas have been synthesized using a triblock copolymer template. Organosilicas with pore sizes ranging from 6-20 mn have been prepared under acidic conditions.

引用

页码：4411 / +

页数：3

共 10 条

[1] Periodic mesoporous organosilicas with organic groups inside the channel walls [J].

Asefa, T ;

MacLachlan, MJ ;

Coombs, N ;

Ozin, GA .

NATURE, 1999, 402 (6764) :867-871

[2] Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks [J].

Inagaki, S ;

Guan, S ;

Fukushima, Y ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9611-9614

[3] Adsorption and thermogravimetric characterization of mesoporous materials with uniform organic-inorganic frameworks [J].

Kruk, M ;

Jaroniec, M ;

Guan, SY ;

Inagaki, S .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (03) :681-689

[4]

MacLachlan MJ, 2000, CHEM-EUR J, V6, P2507, DOI 10.1002/1521-3765(20000717)6:14<2507::AID-CHEM2507>3.0.CO

[5]

2-9

[6] Mesoporous sieves with unified hybrid inorganic/organic frameworks [J].

Melde, BJ ;

Holland, BT ;

Blanford, CF ;

Stein, A .

CHEMISTRY OF MATERIALS, 1999, 11 (11) :3302-3308

[7] Mesocellular siliceous foams with uniformly sized cells and windows [J].

Schmidt-Winkel, P ;

Lukens, WW ;

Zhao, DY ;

Yang, PD ;

Chmelka, BF ;

Stucky, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) :254-255

[8] Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework [J].

Yang, PD ;

Zhao, DY ;

Margolese, DI ;

Chmelka, BF ;

Stucky, GD .

CHEMISTRY OF MATERIALS, 1999, 11 (10) :2813-2826

[9] Periodic mesoporous organosilicas, PMOs:: fusion of organic and inorganic chemistry 'inside' the channel walls of hexagonal mesoporous silica [J].

Yoshina-Ishii, C ;

Asefa, T ;

Coombs, N ;

MacLachlan, MJ ;

Ozin, GA .

CHEMICAL COMMUNICATIONS, 1999, (24) :2539-2540

[10] Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures [J].

Zhao, DY ;

Huo, QS ;

Feng, JL ;

Chmelka, BF ;

Stucky, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (24) :6024-6036

← 1 →