Temperature pulse voltammetry:: hot layer electrodes made by LTCC technology

被引：45

作者：

Voss, T ^{[1
]}

Gründler, P ^{[1
]}

Kirbs, A ^{[1
]}

Flechsig, GU ^{[1
]}

机构：

[1] Univ Rostock, Dept Chem, D-18051 Rostock, Germany

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 1999年 / 1卷 / 09期

关键词：

hot-layer electrochemistry; temperature pulse voltammetry; differential pulse voltammetry; low-temperature cofired ceramics; heated electrodes; redox entropy;

D O I：

10.1016/S1388-2481(99)00079-X

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new electrochemical technique is presented that allows peak-shaped voltammograms to be recorded at local temperature values from room temperature to above boiling point. This new method, temperature pulse voltammetry (TPV), is analogous to differential pulse voltammetry (DPV), but makes use of temperature jumps instead of potential pulses. Fundamentals are presented and potentialities demonstrated. As an example, ferrocyanide is investigated using a new kind of heated electrode on the basis of screen-printed gold layer structures on low-temperature cofired ceramics (LTCC) substrates. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：383 / 388

页数：6

共 10 条

[1] Hot-wire electrodes: Voltammetry above the boiling point [J].