Sensitive nonenzymatic detection of glucose at PtPd/porous holey nitrogen-doped graphene

被引：38

作者：

Salah, Abdulwahab ^{[1
,4
]}

Al-Ansi, Nabilah ^{[1
,4
]}

Adlat, Salah ^{[2
]}

Bawa, Mbage ^{[1
]}

He, Yuanchun ^{[3
]}

Bo, Xiangjie ^{[1
]}

Guo, Liping ^{[1
]}

机构：

[1] Northeast Normal Univ, Fac Chem, 5268 Renmin St, Changchun 130024, Jilin, Peoples R China

[2] Northeast Normal Univ, Sch Life Sci, Key Lab Mol Epigenet MOE, Changchun 130024, Jilin, Peoples R China

[3] Qufu Normal Univ, Coll Chem & Chem Engn, Qufu 273165, Peoples R China

[4] Sanaa Univ, Dept Chem, Sanaa, Yemen

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2019年 / 792卷

基金：

中国国家自然科学基金;

关键词：

Glucose; Porous holey nitrogen-doped graphene; PtPd nanoparticles; Non-enzymatic sensor; POROUS GRAPHENE; ASSISTED SYNTHESIS; PERFORMANCE; ELECTRODE; OXIDE; FABRICATION; COMPOSITES; NANOTUBES; CATALYST; ENERGY;

D O I：

10.1016/j.jallcom.2019.04.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A facile, low cost and effective method was used to synthesize porous holey nitrogen-doped graphene (PHNG) with three-dimensional (3D) structure via direct pyrolysis of a mixture of urea and magnesium acetate tetrahydrate, followed by treating with hydrochloric acid to remove magnesium cations. The unique structure of PHNG significantly decreases the irreversible stacking of graphene nanosheet, favors the exposure of active edge sites, and enables more accessibility for reactants/electrolytes. The PHNG shows porous structure with a large surface area and can serve as support for nanoparticles. PtPd nanoparticles with different ratios were deposited on PHNG surface to synthesize PtPd/PHNG. The PtPd/PHNG-2 shows high direct oxidation activity towards the glucose, achieving a high sensitivity (52.526 mAmM(-1) cm(-2)), wide linear range (100-4000 mM), fast response time (< 3 s), low limit of detection (1.82 mM), as well as high selectivity. (c) 2019 Elsevier B.V. All rights reserved.

引用

页码：50 / 58

页数：9

共 71 条

[51] Nonenzymatic glucose sensor based on ultrasonic-electrode position of bimetallic PtM (M = Ru, Pd and Au) nanoparticles on carbon nanotubes-ionic liquid composite film [J].