Role of sp3/sp2 ratio on the electrocatalytic properties of boron-doped diamond electrodes: A mini review

被引：238
作者：
Garcia-Segura, Sergi [1 ]
dos Santos, Elisama Vieira [1 ]
Martinez-Huitle, Carlos Alberto [1 ]
机构：
[1] Univ Fed Rio Grande do Norte, Inst Quim, Lab Eletroquim Ambiental & Aplicada, BR-59072900 Lagoa Nova, RN, Brazil
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2015年 / 59卷
关键词：
Graphite content; Electro-oxidation; Oxidants; Water treatment; Electroanalysis; SI BDD ANODES; ELECTROCHEMICAL OXIDATION; DOPING LEVEL; HYDROXYL RADICALS; WATER; REACTIVITY; EFFICIENCY; BEHAVIOR; FILMS; DYES;
D O I：
10.1016/j.elecom.2015.07.002
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Recent investigations have confirmed that the sp(3) (diamond)/sp(2) (graphite) ratio has a key role in the electrochemical properties of boron-doped diamond electrodes. The sp(2)-carbon impurities affect the voltammetric background current, potential window and molecular adsorption, influencing the electron-transfer kinetics. This parameter also affects the non-active nature of MD, promoting important variations on the degradation pathway followed during electro-oxidation of organic compounds as well as production of oxidants. These effects are critically discussed and evaluated, providing an up-to-date mini-review. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：52 / 55
页数：4
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