Chan-Lam-Type S-Arylation of Thiols with Boronic Acids at Room Temperature

被引：168

作者：

Xu, Hua-Jian ^{[1
]}

Zhao, Yong-Qiang ^{[1
]}

Feng, Teng ^{[1
]}

Feng, Yi-Si ^{[2
]}

机构：

[1] Hefei Univ Technol, Sch Med Engn, Hefei 230009, Peoples R China

[2] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 06期

基金：

中国国家自然科学基金;

关键词：

CROSS-COUPLING REACTIONS; CATALYZED C-S; SULFUR BOND FORMATION; ARYLBORONIC ACIDS; ARYL HALIDES; LIGAND-FREE; ORGANOBORONIC ACIDS; COPPER CATALYST; PHENYLBORONIC ACIDS; N-CYCLOPROPYLATION;

D O I：

10.1021/jo300100x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this work, an efficient CuSO4-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic system can an tolerate a wide variety of thiols and arylboronic acids in the presence of only 5 mol % of CuSO4 as the catalyst and inexpensive 1,10-phen center dot H2O as the ligand. Moreover, this catalytic system used environment-friendly solvent (EtOH) and oxidant (oxygen).

引用

页码：2878 / 2884

页数：7

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