Thermal decomposition of ethyl parathion

被引:9
作者
Andreozzi, R
Ialongo, G
Marotta, R
Sanchirico, R
机构
[1] Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy
[2] Grp Nazl Difesa Rischi Chim Ind & Ecol, I-80125 Naples, Italy
关键词
thermal decomposition; kinetics; organophosphorus pesticide; adiabatic calorimetry;
D O I
10.1016/S0950-4230(98)00055-2
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The thermal decomposition of ethyl parathion, an organophosphorus pesticide, has been studied by coupling calorimetric and chemical analysis. The decomposition process develops through two exothermic events with production of relevant amounts of uncondensible gases (final pressure 50 bar in an ARC run). A simple autocatalytic kinetic model has been adopted for simulating the first stage of the decomposition process. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:315 / 319
页数:5
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