Chameleon Behavior of a Newly Synthesized Scandium Nitrilimine Derivative

被引：30

作者：

Chu, Jiaxiang ^{[1
]}

Kefalidis, Christos E. ^{[2
,3
]}

Maron, Laurent ^{[2
,3
]}

Leng, Xuebing ^{[1
]}

Chen, Yaofeng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] Univ Toulouse 3, LPCNO, CNRS, F-31077 Toulouse, France

[3] Univ Toulouse 3, INSA, F-31077 Toulouse, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 22期

基金：

中国国家自然科学基金;

关键词：

RAY CRYSTAL-STRUCTURE; X-RAY; ALPHA-DIAZOMETHYL; COMPLEXES; DIAZOALKANES; REACTIVITY; INSERTION; ALUMINUM; 1ST;

D O I：

10.1021/ja403387v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis, structural characterization, and reactivity of the first example of a scandium -substituted nitrilimine are presented. This unique complex exhibits high thermal stability but shows a rich reactivity toward a variety of unsaturated substrates, including aldehyde, ketone, nitrile, and allene derivatives. The versatility of the complex was further highlighted by density functional theory mechanistic studies.

引用

收藏

页码：8165 / 8168

页数：4

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