Di-μ-acetato-κ3O,O′:O;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenan-throline-κ2N,N′)cadmium(II)]

被引：1

作者：

Harvey, Miguel Angel ^{[1
,2
]}

Baggio, Sergio ^{[2
,3
]}

Garland, Maria Teresa ^{[4
,5
]}

Baggio, Ricardo ^{[6
]}

机构：

[1] Univ Nacl Patagonia, Sede Trelew, RA-9100 Trelew, Chubut, Argentina

[2] Consejo Nacl Invest Cient & Tecn, CenPat, RA-9120 Puerto Madryn, Chubut, Argentina

[3] Univ Nacl Patagonia, Sede Puerto, Madryn, Argentina

[4] Univ Chile, Fac Ciencias Fis & Matemat, Dept Fis, Santiago, Chile

[5] CIMAT, Santiago, Chile

[6] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808029462

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cd-2(C2H3O2)(4)(C12H8N2)(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single pi-pi interaction between stacked phen groups [centroid-centroid distance 3.5209 (11) angstrom], leading to a planar structure parallel to (010).

引用

页码：M1450 / U964

页数：10

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