Deciphering DNA-based asymmetric catalysis through intramolecular Friedel-Crafts alkylations

被引：67

作者：

Park, Soyoung ^{[1
]}

Ikehata, Keiichi ^{[1
]}

Watabe, Ryo ^{[1
]}

Hidaka, Yuta ^{[1
]}

Rajendran, Arivazhagan ^{[1
]}

Sugiyama, Hiroshi ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068502, Japan

[3] Japan Sci & Technol Corp JST, CREST, Chiyoda Ku, Tokyo 1020075, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 84期

基金：

日本学术振兴会;

关键词：

DIELS-ALDER REACTION; ORGANIC-SYNTHESIS; WATER; COMPLEXES; INTERCALATORS; VERSATILE; LIGANDS;

D O I：

10.1039/c2cc35625b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe asymmetric intramolecular Friedel-Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.

引用

页码：10398 / 10400

页数：3

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