Mesoporous Mn3O4 Nanobeads/Graphene Hybrids: Facile Gel-Like Film Synthesis, Rational Structure Design, and Excellent Performance for Lithium Storage

被引:37
作者
Su, Liwei [1 ]
Wu, Xianbin [1 ]
Hei, Jinpei [1 ]
Wang, Lianbang [1 ]
Wang, Yuanhao [2 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310014, Zhejiang, Peoples R China
[2] Hong Kong Polytech Univ, Dept Bldg Serv Engn, RERG, Kowloon, Hong Kong, Peoples R China
关键词
CAPACITY ANODE MATERIAL; REDUCED GRAPHENE OXIDE; ION BATTERIES; ELECTROCHEMICAL PROPERTIES; HOLLOW SPHERES; METAL-OXIDES; IN-SITU; NANOCOMPOSITES; NANOSTRUCTURES; COMPOSITES;
D O I
10.1002/ppsc.201500002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous Mn3O4 nanobeads are uniformly dispersed on the surface of graphene via a facile gel-like film method proposed for the first time with the help of H2O2. Graphene can effectively improve the intrinsically poor conductivity of Mn3O4, whereas the mesopores can accommodate the huge volume swings during the repeated lithiation/delithiation processes. The Mn3O4/graphene displays extraordinary cycling stability and excellent rate performance. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:721 / 727
页数:7
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