Glycidyl methacrylate-compatibilized poly(lactic acid)/hemp hurd biocomposites: Processing, crystallization, and thermo-mechanical response

被引:44
作者
Khan, Belas Ahmed [1 ]
Na, Haining [2 ]
Chevali, Venkata [1 ]
Warner, Philip [3 ]
Zhu, Jin [2 ]
Wang, Hao [1 ]
机构
[1] Univ Southern Queensland, Ctr Future Mat, Toowoomba, Qld 4350, Australia
[2] Chinese Acad Sci, Ningbo Ind Technol Inst, Ningbo 315201, Zhejiang, Peoples R China
[3] Ecofibre Ind Operat Pty Ltd, Maleny, Qld 4552, Australia
关键词
Hemp hurd; Poly(lactic acid); Glycidyl methacrylate; Biocomposite; Injection molding; Mechanical properties; MECHANICAL-PROPERTIES; POLYLACTIC ACID; INTERFACIAL ADHESION; THERMAL-STABILITY; INDUSTRIAL HEMP; BY-PRODUCTS; COMPOSITES; FIBER; ENERGY; POLYPROPYLENE;
D O I
10.1016/j.jmst.2017.03.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Poly(lactic acid)-based biocomposites were developed with hemp hurd (Cannabis sativa L.) with grafting-based interfacial compatibilization. Poly(lactic acid) was extruded with hemp hurd and glycidyl methacrylate as the polymer/hurd interfacial compatibilizer, and injection molded. Interfacial compatibility between poly(lactic acid) and hemp hurd increased with grafted glycidyl methacrylate in comparison to the non-compatibilized control, as corroborated by scanning electron microscopy fractography and mechanical analysis, which showed increases in the glycidyl methacrylate-grafted 20% (w/w) hemp hurd/poly(lactic acid) biocomposite, retaining 94% of the neat polymer strength, with increases in crystallinity, and showing a range of thermo-mechanical properties desirable for rigid biocomposite applications. (C) 2017 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
引用
收藏
页码:387 / 397
页数:11
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