Solvent vapor treatment controls surface wettability in PMMA femtosecond-laser-ablated microchannels

被引:20
作者
De Marco, Carmela [1 ]
Eaton, Shane M. [2 ]
Martinez-Vazquez, Rebeca [2 ]
Rampini, Stefano [3 ]
Cerullo, Giulio [2 ,3 ]
Levi, Marinella [1 ]
Turri, Stefano [1 ]
Osellame, Roberto [2 ]
机构
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim Giulio Natta, I-20133 Milan, Italy
[2] CNR, IFN, I-20133 Milan, Italy
[3] Politecn Milan, Dipartimento Fis, I-20133 Milan, Italy
关键词
Femtosecond laser; Ablation; Hydrophilic; Hydrophobic; Passive valve; Microfluidics;
D O I
10.1007/s10404-012-1035-2
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A solvent vapor treatment was applied to femtosecond-laser-ablated microchannels in PMMA to selectively restore the original hydrophilic wetting behavior of the pristine surface. The hydrophobic surface of the microchannels from the submicron porosity induced by ablation becomes smoother and more transparent after the treatment. This simple and low-cost method, together with suitable masking, can produce wettability patterns that may be exploited to develop passive microfluidic elements such as valves and mixers.
引用
收藏
页码:171 / 176
页数:6
相关论文
共 9 条
[1]  
Brandrup J., 1975, POLYM HDB
[2]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[3]   High-Fidelity Solvent-Resistant Replica Molding of Hydrophobic Polymer Surfaces Produced by Femtosecond Laser Nanofabrication [J].
De Marco, Carmela ;
Eaton, Shane M. ;
Levi, Marinella ;
Cerullo, Giulio ;
Turri, Stefano ;
Osellame, Roberto .
LANGMUIR, 2011, 27 (13) :8391-8395
[4]   Surface Properties of Femtosecond Laser Ablated PMMA [J].
De Marco, Carmela ;
Eaton, Shane M. ;
Suriano, Raffaella ;
Turri, Stefano ;
Levi, Marinella ;
Ramponi, Roberta ;
Cerullo, Giulio ;
Osellame, Roberto .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (08) :2377-2384
[5]   Physico-chemical aspects of femtosecond-pulse-laser-induced surface nanostructures [J].
Kautek, W ;
Rudolph, P ;
Daminelli, G ;
Krüger, J .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2005, 81 (01) :65-70
[6]   Imbibition and flow of wetting liquids in noncircular capillaries [J].
Kim, E ;
Whitesides, GM .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (06) :855-863
[7]   Reduction of surface roughness for optical quality microfluidic devices in PMMA and COC [J].
Ogilvie, I. R. G. ;
Sieben, V. J. ;
Floquet, C. F. A. ;
Zmijan, R. ;
Mowlem, M. C. ;
Morgan, H. .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2010, 20 (06)
[8]   Femtosecond laser ablation of polymeric substrates for the fabrication of microfluidic channels [J].
Suriano, Raffaella ;
Kuznetsov, Arseniy ;
Eaton, Shane M. ;
Kiyan, Roman ;
Cerullo, Giulio ;
Osellame, Roberto ;
Chichkov, Boris N. ;
Levi, Marinella ;
Turri, Stefano .
APPLIED SURFACE SCIENCE, 2011, 257 (14) :6243-6250
[9]   Design of shrinkage microvalve in microchannel with hydrophilic and hydrophobic walls [J].
Zhang, Ping ;
Deng, Yongbo ;
Liu, Yongshun ;
Wu, Yihui .
MICROSYSTEM TECHNOLOGIES-MICRO-AND NANOSYSTEMS-INFORMATION STORAGE AND PROCESSING SYSTEMS, 2011, 17 (09) :1491-1495