Iron-Catalyzed C?H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

被引：41

作者：

Garcia-Bosch, Isaac ^{[1
]}

Codola, Zoel ^{[1
]}

Prat, Irene ^{[1
]}

Ribas, Xavi ^{[1
]}

Lloret-Fillol, Julio ^{[1
]}

Costas, Miquel ^{[1
]}

机构：

[1] Univ Girona, Dept Chem, Qbis Grp, Girona 17071, Catalonia, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 42期

基金：

欧洲研究理事会;

关键词：

bioinorganic chemistry; C?H activation; metal-oxo compounds; N ligands; oxidation; water oxidation; ALKANE HYDROXYLATION; DIOXYGEN ACTIVATION; IRIDIUM COMPLEXES; CRYSTAL-STRUCTURE; OXIDATION; OXO; EPOXIDATION; CHEMISTRY; ENZYMES; MODELS;

D O I：

10.1002/chem.201202147

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bioinspired oxidation: The hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2( Me,HPyTACN)] (1) as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of C-H bonds and C=C bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH 2)(Me,HPyTACN)]+. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13269 / 13273

页数：5

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