Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries

被引：832
|
作者：
Jian, Zelang [1 ,2 ]
Han, Wenze [1 ,3 ]
Lu, Xia [1 ]
Yang, Huaixin [1 ]
Hu, Yong-Sheng [1 ]
Zhou, Jing [2 ]
Zhou, Zhibin [4 ]
Li, Jianqi [1 ]
Chen, Wen [2 ]
Chen, Dongfeng [3 ]
Chen, Liquan [1 ]
机构：
[1] Chinese Acad Sci, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing Natl Lab Condensed Matter Phys,Inst Phys, Beijing 100190, Peoples R China
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
[3] China Inst Atom Energy, Beijing 102413, Peoples R China
[4] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
来源：
ADVANCED ENERGY MATERIALS | 2013年 / 3卷 / 02期
关键词：
Na3V2(PO4)3; sodium-ion batteries; storage mechanism; in situ XRD; ANODE MATERIALS; ELECTRODES; PHOSPHATES; CHALLENGES; CARBONATE; INSERTION;
D O I：
10.1002/aenm.201200558
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A Na3V2(PO4)3/C composite with 3.8 wt.% carbon, which was synthesized by a one-step solid state reaction, exhibits Na storage capacity of 107 mAh g-1 and high coulombic efficiency of 99.8% in a new NaFSI/PC electrolyte. In situ XRD results reveal its sodium storage mechanism as a typical two-phase reaction from the Na 3V2(PO4)3 to NaV2(PO 4)3 phases with 8.26% volume variation. These desired properties make it very promising for application in room-temperature sodium-ion batteries. © 2013 WILEY-VCH Verlag GmbH and Co.
引用
收藏
页码：156 / 160
页数：5
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