共 49 条
Ni-Cu bimetallic catalysts on Yttria-stabilized zirconia for hydrogen production from ethanol steam reforming
被引:44
作者:
Chen, Fangyuan
[1
,2
]
Tao, Yongwen
[2
]
Ling, Huajuan
[2
]
Zhou, Cuifeng
[2
]
Liu, Zongwen
[2
]
Huang, Jun
[2
]
Yu, Aibing
[3
]
机构:
[1] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China
[2] Univ Sydney, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia
[3] Monash Univ, ARC Hub Computat Particle Technol, Clayton, Vic 3800, Australia
来源:
关键词:
Ethanol steam reforming;
Hydrogen production;
Stability;
Ni and Cu;
Bimetallic catalysts;
WATER-GAS SHIFT;
XPS;
SPECTROSCOPY;
PRETREATMENT;
PRECURSORS;
OXIDATION;
METHANE;
XRD;
D O I:
10.1016/j.fuel.2020.118612
中图分类号:
TE [石油、天然气工业];
TK [能源与动力工程];
学科分类号:
0807 ;
0820 ;
摘要:
One of the key challenges in catalytic ethanol steam reforming (ESR) is the ease of deactivation of the catalysts caused by metal sintering and carbon deposition. In this study, bimetallic Ni-Cu catalysts supported on Yttria stabilized zirconia (YSZ) have been prepared for ESR. Bimetallic Ni-Cu catalysts were active for ESR and the addition of Cu can improve the Ni performance and stability of the catalysts in ESR. Adding a small amount of Cu to the catalyst successfully led to formation of Cu-Ni alloy, which is efficient for improving reducibility of the catalyst. However, high Cu content limited the activity of the catalysts due to the lack of exposed active sites of Ni and Cu. In ESR, Ni was proposed to be responsible for C-C bond cleavage while Cu was for the promotion of WGS. YSZ has very limited role in reducing coke formation as the catalyst support though it has high surface oxygen mobility, which is indicated by the serious deactivation by coke formation on Ni/YSZ monometallic catalyst. However, Cu addition on bimetallic Ni-Cu catalysts is proved to be effective to improve stability of the catalysts by reducing coke deposition. Among all the catalysts, Cu1Ni9/YSZ exhibited superior performance and stability with negligible activity loss during 20 h ESR reaction at 450 degrees C and 650 degrees C, respectively.
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页数:10
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