A simple and efficient iron-catalyzed intramolecular hydroamination of unactivated olefins

被引：196
作者：
Komeyama, Kimihiro [1 ]
Morimoto, Takayuki [1 ]
Takaki, Ken [1 ]
机构：
[1] Hiroshima Univ, Grad Sch Engn, Dept Chem & Chem Engn, Higashihiroshima 7398527, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期
关键词：
alkenes; homogeneous catalysis; hydroamination; iron; nitrogen heterocycles;
D O I：
10.1002/anie.200503789
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) A new catalytic activity of iron salts for intramolecular hydroamination is revealed. A number of aminoolefins underwent the reaction under mild conditions to form the corresponding pyrrolidine derivatives in good yield. The reaction displayed good functional-group compatibility and resistance to air and moisture. (Ts = e-toluenesulfonyl). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2938 / 2941
页数：4
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