Double-Decker-Type Dinuclear Nickel Catalyst for Olefin Polymerization: Efficient Incorporation of Functional Co-monomers

被引：133

作者：

Takeuchi, Daisuke ^{[1
]}

Chiba, Yuriko ^{[1
]}

Takano, Shigenaga ^{[1
]}

Osakada, Kohtaro ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 48期

关键词：

copolymerization; homogeneous catalysis; nickel; polymerization; transition metals; CONSTRAINED-GEOMETRY CATALYST; BINUCLEAR NEUTRAL NICKEL; ETHYLENE POLYMERIZATION; COMONOMER ENCHAINMENT; NONCONJUGATED DIENES; MOLECULAR-WEIGHT; NORBORNENE COPOLYMERIZATIONS; PHENOXYIMINATO CATALYSTS; ZIRCONOCENE CATALYSTS; COBALT COMPLEXES;

D O I：

10.1002/anie.201307741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dinuclear Ni complex with a double-decker structure (see scheme) and a short Ni-Ni distance promotes the copolymerization of ethylene with functional monomers. Matching of the Ni-Ni distance with the co-monomer structure resulted in polymers containing a high density of the co-monomer unit. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12536 / 12540

页数：5

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