One-Pot Synthesis, Crystal Structures and Topology Analysis of Two Nickel(II) Complexes Based on 1,3,5-Benzenetricarboxylic Acid

被引:5
|
作者
Zhao, Ying-Na [1 ]
Wang, Yan-Yan [1 ]
Zhao, Yan-Qin [1 ]
Cui, Guang-Hua [1 ]
机构
[1] Hebei United Univ, Coll Chem Engn, Tangshan 063009, Hebei, Peoples R China
关键词
Complexes; One-pot synthesis; Topology analysis; Supramolecular network;
D O I
10.1007/s10870-013-0450-x
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The one-pot solvothermal reaction of Ni(NO3)(2) with 1,3,5-benzenetricarboxylic acid (H(3)btc) and 4,4'-bis(imidazol-1-yl)benzene (bibp) affords two coordination compounds. The H(3)btc ligand is deprotonated step-by-step, and connects Ni-II ions into two different valence-bonded structures (the binuclear molecule and 2D (4,4) grid) under the cooperation of bibp. Hydrogen bonds have been deeply investigated, and yield an interpenetrating binodal (3,5)-connected supramolecular network with the Schafli symbol of [4(2).6]center dot[4(2).6(5).8(3)] and interdigitating binodal (4,6)-connected supramolecular network with the Schafli symbol of [4(4).5(2)]center dot[4(4).5(6).6(4).7], respectively.
引用
收藏
页码:502 / 507
页数:6
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