Visible-light-enhanced hydrogen evolution from catalytic hydrolysis of ammonia borane using Ru nanoparticles supported on CdS-modified graphitic carbon nitride

被引：7

作者：

Wei, Lei ^{[1
]}

Zhang, Yani ^{[1
]}

Liu, Jingyang ^{[1
]}

Li, Yepei ^{[1
]}

Lu, Yanhong ^{[1
]}

Liu, Hongyan ^{[1
]}

机构：

[1] Langfang Normal Univ, Coll Chem & Mat Sci, Langfang 065000, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2022年 / 46卷 / 41期

关键词：

METAL-ORGANIC FRAMEWORK; EFFICIENT CATALYSTS; RUTHENIUM NANOPARTICLES; FACILE SYNTHESIS; H-2; PRODUCTION; QUANTUM DOTS; DEHYDROGENATION; GENERATION; PHOTOCATALYSTS; NANOCOMPOSITES;

D O I：

10.1039/d2nj03770j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalytic hydrolysis of ammonia borane (AB) has been regarded as an efficient and safe approach for hydrogen evolution. In this work, an optimized CdS/C3N4 heterojunction was employed as the photoactive support, and ultrafine Ru nanoparticles were deposited by impregnation and chemical reduction, yielding a Ru/CdS/C3N4 photocatalyst for AB hydrolysis. A series of advanced techniques were used for material characterization involving micromorphology, phase structure, chemical composition, and optical properties. Compared with raw g-C3N4, the heterojunction possesses a stronger absorption ability in the visible-light region, which endows the prepared Ru/CdS/C3N4 with excellent photocatalytic activity. For AB hydrolysis, visible-light-enhanced TOF was measured to be 132.9 min(-1) (25 degrees C), which is 2.2-fold higher than the value obtained under dark conditions. The AB hydrolysis behavior and photocatalysis mechanism were investigated in detail. Additionally, Ru/CdS/C3N4 retains 86% of the initial activity after recycling five times, showing that the photocatalyst has a good prospect for practical applications.

引用

页码：19731 / 19739

页数：9

共 43 条

[1] Hydrogen as an energy vector [J].

Abdin, Zainul ;

Zafaranloo, Ali ;

Rafiee, Ahmad ;

Merida, Walter ;

Lipinski, Wojciech ;

Khalilpour, Kaveh R. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2020, 120

[2] Ammonia borane as hydrogen storage materials [J].

Akbayrak, Serdar ;

Ozkar, Saint .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (40) :18592-18606

[3] A facile synthesis of nearly monodisperse ruthenium nanoparticles and their catalysis in the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage [J].

Can, Hasan ;

Metin, Onder .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 125 :304-310

[4] Graphene supported Ru@Co core-shell nanoparticles as efficient catalysts for hydrogen generation from hydrolysis of ammonia borane and methylamine borane [J].

Cao, Nan ;

Su, Jun ;

Luo, Wei ;

Cheng, Gongzhen .

CATALYSIS COMMUNICATIONS, 2014, 43 :47-51

[5] One-step synthesis of graphene supported Ru nanoparticles as efficient catalysts for hydrolytic dehydrogenation of ammonia borane [J].

Cao, Nan ;

Luo, Wei ;

Cheng, Gongzhen .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (27) :11964-11972

[6] CdS-modified one-dimensional g-C3N4 porous nanotubes for efficient visible-light photocatalytic conversion [J].

Chong, Ben ;

Chen, Lei ;

Han, Dezhi ;

Wang, Liang ;

Feng, Lijuan ;

Li, Qin ;

Li, Chunhu ;

Wang, Wentai .

CHINESE JOURNAL OF CATALYSIS, 2019, 40 (06) :959-968

[7] Ammonia borane, a material with exceptional properties for chemical hydrogen storage [J].

Demirci, Umit B. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (15) :9978-10013

[8] Salt template-assisted in situ construction of Ru nanoclusters and porous carbon: excellent catalysts toward hydrogen evolution, ammonia-borane hydrolysis, and 4-nitrophenol reduction [J].

Ding, Rong ;

Chen, Qian ;

Luo, Qian ;

Zhou, Lingxi ;

Wang, Yi ;

Zhang, Yun ;

Fan, Guangyin .

GREEN CHEMISTRY, 2020, 22 (03) :835-842

[9] Hydrogen futures: toward a sustainable energy system [J].

Dunn, S .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (03) :235-264

[10] Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia-borane: High activity and long lifetime [J].

Durap, Feyyaz ;

Zahmakiran, Mehmet ;

Ozkar, Saim .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (17) :7223-7230

← 1 2 3 4 5 →