1H NMR study of distribution of functional groups in carboxymethyl dextran

被引：0
|
作者：
Sokolov, VB [1 ]
Krasnov, KA [1 ]
Matyushichev, IY [1 ]
Passet, BV [1 ]
机构：
[1] St Petersburg State Acad Pharmaceut Chem, St Petersburg, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 1999年 / 72卷 / 04期
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D O I：
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中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The distribution of functional groups in a monomeric unit of carboxymethyl dextran was studied by H-1 NMR. The distribution of carboxymethyl groups between the 2-, 3-, and 4-positions of the glucopyranose unit of dextran was studied as a function of the total degree of substitution. The activity constants were determined for hydroxyls in 2-, 3-, and 4-positions of the unit in carboxymethylation reaction.
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页码：701 / 703
页数：3
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