Fabrication of highly fluorescent perylene bisimide nanofibers through interfacial self-assembly

被引：33

作者：

Boobalan, G. ^{[1
]}

Imran, P. K. M. ^{[2
]}

Manoharan, C. ^{[3
]}

Nagarajan, S. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India

[2] Islamiah Coll, Dept Chem, Vaniyambadi 635731, India

[3] Annamalai Univ, Dept Phys, Annamalainagar 608002, Tamil Nadu, India

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2013年 / 393卷

关键词：

Perylene diimide; Self-assembly; Aggregation; Nanofibers; Luminescence; SEMICONDUCTORS; SUBSTITUENTS; ORGANIZATION; NANORIBBONS; CRYSTALS; MOBILITY;

D O I：

10.1016/j.jcis.2012.10.053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Perylene diimides are typical n-type organic semiconductors with interesting optical and electronic properties. Versatile properties of these compounds are deeply related to the morphologies of the self-assembled nanostructures. Self-assembled strong red fluorescent nanofibers of N,N'-bis(1-dodecyl)perylene-3,4,9,10-tetracarboxylic diimide (D-PTCDI) were successfully prepared by a solution based phase-transfer method. Morphology of the nanostructure was characterized by optical, fluorescence, scanning, and transmission electron microscopic techniques. Observed molecular self-assembly was supported by the computational predictions. Thin film of the D-PTCDI was casted on glass substrate by spincoating. UV-vis absorption maximum of the thin film was shifted to longer wavelength than in solution. Conducting properties of the thin films were evaluated by current-voltage measurements. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：377 / 383

页数：7

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