The Construction of a Novel Bromido- and Azido-Bridged Dinuclear Copper(II) Complex Derived From 4-Chloro-2-[(2-hydroxyethylimino)methyl]phenol

被引：0

作者：

Qian, Shao-Song ^{[1
]}

Li, Hai-Hua ^{[2
]}

Cheng, Xiao-Shan ^{[2
]}

You, Zhong-Lu ^{[2
]}

Zhu, Hai-Liang ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Life Sci, Zibo 255049, Peoples R China

[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 06期

关键词：

copper complex; crystal structure; dinuclear complex; Schiff base; CRYSTAL-STRUCTURES; SCHIFF-BASES;

D O I：

10.1080/15533174.2012.753623

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel bromido- and azido-bridged dinuclear copper(II) complex, [Cu2Br2L2]center dot[Cu2Br(N3)L2]center dot H2O, where L is the deprotonated form of the Schiff base 4-chloro-2-[(2-hydroxyethylimino)methyl]phenol, has been prepared and structurally characterized by elemental analysis, IR spectra, and single crystal X-ray crystallography. Each Cu atom in the complex is coordinated by three donor atoms of Schiff base ligand and by two bridging atoms, forming a square pyramidal geometry. The bromide and azide ligands are preferred bridging groups for the construction of dinuclear copper complexes with Schiff bases.

引用

页码：687 / 690

页数：4

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