Studies on modified borosilicate glass for enhancement of solubility of molybdenum

被引：27
|
作者：
Prakash, Amrita Dhara [1 ,2 ]
Singh, Manjeet [2 ,3 ]
Mishra, R. K. [4 ]
Valsala, T. P. [1 ]
Tyagi, A. K. [2 ,5 ]
Sarkar, Arnab [2 ,3 ]
Kaushik, C. P. [2 ,4 ]
机构：
[1] Bhabha Atom Res Ctr, Tarapur Waste Management Plant, Tarapur 401504, India
[2] Homi Bhabha Natl Inst, Mumbai 400094, Maharashtra, India
[3] Bhabha Atom Res Ctr, Div Fuel Chem, Mumbai 400085, Maharashtra, India
[4] Bhabha Atom Res Ctr, Waste Management Div, Mumbai 400085, Maharashtra, India
[5] Bhabha Atom Res Ctr, Div Chem, Trombay 400085, India
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2019年 / 510卷
关键词：
Phosphate containing Borosilicate glass; Molybdenum oxide; High level radioactive liquid waste (HLW); Laser induced breakdown spectroscopy (LIBS) studies; Glass transition temperature; PHOSPHATE-GLASSES; MAS NMR; CRYSTALLIZATION; IMMOBILIZATION; SULFATE; MELT;
D O I：
10.1016/j.jnoncrysol.2019.01.019
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Molybdenum is a fission product with high fission yield, present in High Level Liquid Waste (HLW). Presently HLW is confined in borosilicate glass matrix. To enhance the solubility of MoO3, different host glass matrices containing different amount of MoO3 were prepared and studied. Phosphate containing borosilicate glass showed increased solubility for MoO3. X-ray Diffraction (XRD) studies were carried out to check for presence of crystalline phase within glass samples. Phosphate containing glass samples could accommodate 4 mol% of MoO3 whereas in absence of phosphate only 1 mol% of MoO3 could be accommodated in borosilicate glass. Laser induced breakdown spectroscopy (LIBS) data was employed to confirm the homogeneity of MoO(3 )within the glass sample. Glass transition temperature was also observed for all the glass samples to study the effect of MoO3 on thermal stability.
引用
收藏
页码：172 / 178
页数：7
相关论文
共 50 条
  • [1] Thermal and Mechanical Studies of Cerium Molybdenum Borosilicate Glasses and Glass–Ceramics
    Kh. S. Shaaban
    B. M. Alotaibi
    Z. A. Alrowaili
    M. S. Al-Buriahi
    A. Ashour
    Sayed Yousef
    Silicon, 2023, 15 : 5233 - 5243
  • [2] Thermal and Mechanical Studies of Cerium Molybdenum Borosilicate Glasses and Glass-Ceramics
    Shaaban, Kh. S.
    Alotaibi, B. M.
    Alrowaili, Z. A.
    Al-Buriahi, M. S.
    Ashour, A.
    Yousef, Sayed
    SILICON, 2023, 15 (12) : 5233 - 5243
  • [3] SOLUBILITY OF RUO2 IN A PB BOROSILICATE GLASS
    PRABHU, A
    FULLER, GL
    VEST, RW
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1974, 57 (09) : 408 - 409
  • [4] Enhancing cerium and plutonium solubility by reduction in borosilicate glass
    Cachia, J. -N.
    Deschanels, X.
    Den Auwer, C.
    Pinet, O.
    Phalippou, J.
    Hennig, C.
    Scheinost, A.
    JOURNAL OF NUCLEAR MATERIALS, 2006, 352 (1-3) : 182 - 189
  • [5] Durability of molybdenum disilicide in molten alkali borosilicate glass
    Los Alamos National Laboratory, Mat. Sci. Technol. Div., P.O. B., Los Alamos, NM 87545, United States
    Mater. Sci. Eng. A, 1-2 (278-283):
  • [6] Durability of molybdenum disilicide in molten alkali borosilicate glass
    Park, YS
    Butt, DP
    Castro, R
    Petrovic, J
    Johnson, W
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 261 (1-2): : 278 - 283
  • [7] FURTHER STUDIES IN ANNEALING OF A BOROSILICATE GLASS
    SPINNER, S
    NAPOLITA.A
    JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1966, A 70 (02): : 147 - +
  • [8] Actinide solubility in lanthanide borosilicate glass for possible immobilization and disposition
    Meaker, TF
    Peeler, DK
    Marra, JC
    Pareizs, JM
    Ramsey, WG
    SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XX, 1997, 465 : 1281 - 1286
  • [9] Ballistic impact studies of a borosilicate glass
    Forde, L. C.
    Proud, W. G.
    Walley, S. M.
    Church, P. D.
    Cullis, I. G.
    INTERNATIONAL JOURNAL OF IMPACT ENGINEERING, 2010, 37 (05) : 568 - 578
  • [10] REDOX-CONTROLLED SOLUBILITY OF PALLADIUM IN A BOROSILICATE GLASS MELT
    SCHREIBER, HD
    HARVILLE, TR
    DAMRON, GN
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (05) : 1435 - 1437
12345