A biocatalytic hydrogenation of carboxylic acids

被引：51
作者：
Ni, Yan [1 ,2 ]
Hagedoorn, Peter-Leon [1 ]
Xu, Jian-He [2 ]
Arends, Isabel W. C. E. [1 ]
Hollmann, Frank [1 ]
机构：
[1] Delft Univ Technol, Dept Biotechnol, NL-2628 BL Delft, Netherlands
[2] E China Univ Sci & Technol, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 99期
关键词：
CATALYZED CHEMOSELECTIVE REDUCTION; ARCHAEON PYROCOCCUS-FURIOSUS; TUNGSTEN-CONTAINING ENZYME; ALDEHYDE OXIDOREDUCTASE; HYPERTHERMOPHILIC ARCHAEON; FERREDOXIN OXIDOREDUCTASE; RALSTONIA EUTROPHA; ORGANIC-SOLVENTS; MICROORGANISMS; ALCOHOLS;
D O I：
10.1039/c2cc36479d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hyperthermophile Pyrococcus furiosus catalyses the hydrogenation of a broad range of carboxylic acids selectively to the corresponding primary alcohols. Other functional groups such as isolated CQC-double bonds are not touched. The chemo-selectivity of the carboxylate reduction may be directed towards aldehydes by simple medium engineering.
引用
收藏
页码：12056 / 12058
页数：3
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