Silver-Catalyzed Decarboxylative Radical Addition/Cyclization of Oxamic Acids with Alkenes towards Quinolin-2-ones

被引：9

作者：

Jin, Chengan ^{[1
]}

He, Jing-Yao ^{[1
]}

Bai, Qi-Fan ^{[1
]}

Feng, Gaofeng ^{[1
]}

机构：

[1] Shaoxing Univ, Coll Chem & Chem Engn, Shaoxing 312000, Peoples R China

来源：

SYNLETT | 2020年 / 31卷 / 15期

基金：

中国国家自然科学基金;

关键词：

silver catalysis; addition; cyclization; tandem reaction; oxamic acids; quinolinones; CARBAMOYL RADICALS; N-PHENYLCINNAMAMIDES; TANDEM CYCLIZATION; H BOND; DERIVATIVES; FUNCTIONALIZATION; ARYLCINNAMAMIDES; CINNAMAMIDES; ACTIVATION; REACTIVITY;

D O I：

10.1055/s-0040-1707891

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient silver-catalyzed tandem decarboxylative radical addition/cyclization of oxamic acids with alkenes has been developed. This method provides a novel and straightforward protocol toward a variety of 4-aryl-3,4-dihydroquinolin-2(1H)-ones, 4-(alpha-carbonyl)-3,4-dihydroquinolin-2(1H)-ones, and quinolin-2(1H)-ones in aqueous solution.

引用

页码：1517 / 1522

页数：6

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