Development of a recyclable fluorous chiral phase-transfer catalyst:: Application to the catalytic asymmetric synthesis of α-amino acids

被引：46

作者：

Shirakawa, S ^{[1
]}

Tanaka, Y ^{[1
]}

Maruoka, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 09期

关键词：

D O I：

10.1021/ol049724w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A recyclable fluorous chiral phase-transfer catalyst was synthesized and successfully applied for the catalytic asymmetric synthesis of both natural and unnatural alpha-amino acids. The reaction involves alkylation of a glycine derivative followed by extractive recovery of the chiral phase-transfer catalyst using fluorous solvent.

引用

页码：1429 / 1431

页数：3

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