New copolymer of poly(N-vinylcarbazole) and poly(p-phenylenevinylene) for optoelectronic devices

被引：32
作者：
Mbarek, Mohamed [1 ]
Massuyeau, Florian [2 ]
Duvail, Jean-Luc [2 ]
Wery, Jany [2 ]
Faulques, Eric [2 ]
Alimi, Kamel [1 ]
机构：
[1] Univ Monastir Tunisie, Unite Rech Mat Nouveaux & Dispositifs Elect Organ, Fac Sci Monastir, Tunis, Tunisia
[2] CNRS, Inst Mat Jean Rouxel, UMR 6502, F-44322 Nantes 3, France
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2013年 / 130卷 / 04期
关键词：
copolymers; grafting; optical properties; RECHARGEABLE LITHIUM BATTERIES; POLYN-VINYLCARBAZOLE; CONDUCTING NANOCOMPOSITE; N-VINYLCARBAZOLE; GRAFT COPOLYMER; PPV; COMPOSITE; VINYLENE); POLYMERS; ELECTROLUMINESCENCE;
D O I：
10.1002/app.39496
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel diblock copolymer based on poly(N-vinylcarbazole) PVK and poly(p-phenylenevinylene) (PPV) precursor was synthesized by oxidative cross-linking. The grafting of PPV with PVK moieties was elucidated by infrared absorption analysis. A structural study by X-ray diffraction and a morphological study of the copolymer by scanning and transmission electron microscopy reveal a multiscale one-dimensional self-organization both at the molecular and at the sub-micrometric level. The resulting copolymer exhibits original optical properties compared to those of PVK and PPV ones and presents an improved thermal behavior. (c) 2013 Wiley Periodicals, Inc.
引用
收藏
页码：2839 / 2847
页数：9
相关论文
共 37 条
  • [1] Electrical and optical properties of PPV and single-walled carbon nanotubes composite films
    Aarab, H
    Baïtoul, M
    Wéry, J
    Almairac, R
    Lefrant, S
    Faulques, E
    Duvail, JL
    Hamedoun, M
    [J]. SYNTHETIC METALS, 2005, 155 (01) : 63 - 67
  • [2] Poly(N-vinyl carbazole) and carbon nanotubes based composites and their application to rechargeable lithium batteries
    Baibarac, M.
    Lira-Cantu, M.
    Sol, J. Oro
    Baltog, I.
    Casan-Pastor, N.
    Gomez-Romero, P.
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (11-12) : 2556 - 2563
  • [3] A conducting polyN-vinylcarbazole-molybdenum blues nanocomposite from N-vinylcarbazole-MoVI polymerization system
    Ballav, N
    Biswas, M
    [J]. SYNTHETIC METALS, 2005, 149 (2-3) : 109 - 114
  • [4] Preparation and characterization of a conducting nanocomposite of polyN-vinylcarbazole with acetylene black
    Ballav, N
    Maity, A
    Biswas, M
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2004, 87 (01) : 120 - 126
  • [5] A water-dispersible conducting nanocomposite from suspension polymerisation of thiophene in presence of N-vinylcarbazole
    Ballav, N
    Biswas, M
    [J]. POLYMER INTERNATIONAL, 2004, 53 (02) : 198 - 203
  • [6] A conducting composite of polyN-vinylcarbazole and polythiophene
    Ballav, N
    Biswas, M
    [J]. SYNTHETIC METALS, 2003, 132 (02) : 213 - 218
  • [7] Photogeneration and photovoltaic effect in poly(N-vinylcarbazole): TiO2 bulk-heterojunction elaborated by hydrolysis-condensation reactions of TiO2 precursors
    Barlier, Vincent
    Bounor-Legare, Veronique
    Boiteux, Gisele
    Davenas, Joel
    Slazak, Agnieszka
    Rybak, Andrzej
    Jung, Jaroslaw
    [J]. SYNTHETIC METALS, 2009, 159 (5-6) : 508 - 512
  • [8] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS
    BURROUGHES, JH
    BRADLEY, DDC
    BROWN, AR
    MARKS, RN
    MACKAY, K
    FRIEND, RH
    BURN, PL
    HOLMES, AB
    [J]. NATURE, 1990, 347 (6293) : 539 - 541
  • [9] Characterization of N-vinyl carbazole/vinyl 4-tert-butyl-benzoate copolymers of several molar compositions: SEC, DSC and intramolecular excimers in dilute solutions
    Carmona, Thais
    Fernandez-Pena, Natali
    Pilar Tarazona, M.
    Saiz, Enrique
    Mendicuti, Francisco
    [J]. EUROPEAN POLYMER JOURNAL, 2010, 46 (08) : 1796 - 1809
  • [10] A study of the relationship between the electroluminescence characteristics and compositions of PPV-PVA-based polymers
    Chang, WP
    Whang, WT
    [J]. POLYMER, 1996, 37 (16) : 3493 - 3499
1234