Improving the characteristics of an organic nano floating gate memory by a self-assembled monolayer

被引:28
作者
Chang, Hsuan-Chun [2 ]
Lee, Wen-Ya [2 ]
Tai, Yian [1 ]
Wu, Kuang-Wei [1 ]
Chen, Wen-Chang [2 ]
机构
[1] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 106, Taiwan
[2] Natl Taiwan Univ, Dept Chem Engn, Taipei 106, Taiwan
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; ALTERNATING CONJUGATED COPOLYMERS; ELECTRICAL BISTABILITY; CHARGE-TRANSFER; DONOR; PERFORMANCE; VOLTAGE; MOBILITY; DEVICES;
D O I
10.1039/c2nr30882g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate a novel approach to improve the characteristics of the gold nanoparticle-based organic transistor memory devices by using self-assembled monolayers (SAM) with different functional groups as interfacial modifier. SAM-based interfacial engineering significantly improved the hysteresis, memory window, and on/off ratio of a nano floating gate memory (NFGM) at zero gate voltage. This NFGM showed a large memory window of up to 190 V and on/off current ratio of 10(5) during writing and erasing with an operation voltage of 100 V of gate bias in a short time, less than 1 s. Furthermore, the devices show excellent nonvolatile behavior for bistable switching. The ON and OFF state can be stably maintained for 10(3) s with an I-on/I-off current ratio of 10(6) for a pentafluorophenyl trimethoxysilane modified device. The results suggested the importance of SAM-modified interface for the memory performance of NFGMs.
引用
收藏
页码:6629 / 6636
页数:8
相关论文
共 71 条
[11]   Organic donor-acceptor system exhibiting electrical bistability for use in memory devices [J].
Chu, CW ;
Ouyang, J ;
Tseng, HH ;
Yang, Y .
ADVANCED MATERIALS, 2005, 17 (11) :1440-+
[12]   Electronically configurable molecular-based logic gates [J].
Collier, CP ;
Wong, EW ;
Belohradsky, M ;
Raymo, FM ;
Stoddart, JF ;
Kuekes, PJ ;
Williams, RS ;
Heath, JR .
SCIENCE, 1999, 285 (5426) :391-394
[13]   Large-scale complementary integrated circuits based on organic transistors [J].
Crone, B ;
Dodabalapur, A ;
Lin, YY ;
Filas, RW ;
Bao, Z ;
LaDuca, A ;
Sarpeshkar, R ;
Katz, HE ;
Li, W .
NATURE, 2000, 403 (6769) :521-523
[14]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[15]  
2-9
[16]   ORGANIZATION OF AU COLLOIDS AS MONOLAYER FILMS ONTO ITO GLASS SURFACES - APPLICATION OF THE METAL COLLOID FILMS AS BASE INTERFACES TO CONSTRUCT REDOX-ACTIVE MONOLAYERS [J].
DORON, A ;
KATZ, E ;
WILLNER, I .
LANGMUIR, 1995, 11 (04) :1313-1317
[17]   Charge-dipole model for the universal field dependence of mobilities in molecularly doped polymers [J].
Dunlap, DH ;
Parris, PE ;
Kenkre, VM .
PHYSICAL REVIEW LETTERS, 1996, 77 (03) :542-545
[18]   New Donor-Acceptor Random Copolymers with Pendent Triphenylamine and 1,3,4-Oxadiazole for High-Performance Memory Device Applications [J].
Fang, Yi-Kai ;
Liu, Cheng-Liang ;
Yang, Guei-Yu ;
Chen, Po-Cheng ;
Chen, Wen-Chang .
MACROMOLECULES, 2011, 44 (08) :2604-2612
[19]   New random copolymers with pendant carbazole donor and 1,3,4-oxadiazole acceptor for high performance memory device applications [J].
Fang, Yi-Kai ;
Liu, Cheng-Liang ;
Chen, Wen-Chang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) :4778-4786
[20]   Synthesis, Morphology, and Properties of Poly(3-hexylthiophene)-block-Poly(vinylphenyl oxadiazole) Donor-Acceptor Rod-Coil Block Copolymers and Their Memory Device Applications [J].
Fang, Yi-Kai ;
Liu, Cheng-Liang ;
Li, Chaoxu ;
Lin, Chih-Jung ;
Mezzenga, Raffaele ;
Chen, Wen-Chang .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (18) :3012-3024