A practical two-step synthesis of tetraselenafulvalene (TSF)

被引:7
作者
Takimiya, K [1 ]
Jeon, HJ [1 ]
Otsubo, T [1 ]
机构
[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan
来源
SYNTHESIS-STUTTGART | 2005年 / 16期
关键词
tetraselenafulvalenes; selenium; sodium acetylide; electron donors;
D O I
10.1055/s-2005-872117
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The preparation of tetraselenafulvalene (TSF) from commercially available sodium acetylide in xylene-light mineral oil and selenium powder is described.
引用
收藏
页码:2810 / 2813
页数:4
相关论文
共 35 条
  • [31] Synthesis of Two Isomers of pyrido/benzo[b][1,4]selenazines: A Selective Catalyst-Dependent Formation of C-N and C-Se Bonds
    Santos, Felipe B.
    Pezzini, Emily
    Cargnelutti, Roberta
    Penteado, Filipe
    Schumacher, Ricardo F.
    ADVANCED SYNTHESIS & CATALYSIS, 2023, 365 (23) : 4286 - 4292
  • [32] [Te8]2[Ta4O4Cl16]: A Two-dimensional Tellurium Polycation obtained via Ionic Liquid-Based Synthesis
    Freudenmann, Dominic
    Feldmann, Claus
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (11): : 1481 - 1485
  • [33] Cubane complexes with two (or more) Group 14-Group 16 double bonds:: Synthesis and X-ray structures of Sn4Se2(NtBu)4 and Ge4Se3(NtBu)4
    Chivers, T
    Clark, TJ
    Krahn, M
    Parvez, M
    Schatte, G
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (10) : 1857 - 1860
  • [34] Efficient and practical synthesis of modular chiral β-organochalcogeno amines, ArYCH2CH(R)NH2, and single crystal structures of (S) - MsOCH2CH(Bz)NH3+ • Cl- and (R)-MsOCH2CH(Ph)NH3+ •Cl-
    Revanna, Rajegowda H.
    Kumar, Raghavendra P.
    Hosamani, Amar
    Siddagangaiah, Palakshamurthy B.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 799-800 : 61 - 69
  • [35] Methanolothermal synthesis of Rb3AsSe4 center dot 2 Se-6 and Cs3AsSe4 center dot 2 Cs2As2Se4 center dot 6 Te4Se2. Two selenidoarsenates with six-membered chalcogen rings
    Wachhold, M
    Sheldrick, WS
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (02): : 169 - 175