In situ generation of a high-performance Pd-polypyrrole composite with multi-functional catalytic properties

被引:57
作者
Choudhary, Meenakshi [1 ]
Ul Islam, Rafique [1 ]
Witcomb, Michael J. [2 ]
Mallick, Kaushik [1 ]
机构
[1] Univ Johannesburg, Dept Chem, ZA-2006 Auckland Pk, South Africa
[2] Univ Witwatersrand, DST NRF Ctr Excellence Strong Mat, ZA-2050 Johannesburg, South Africa
基金
新加坡国家研究基金会;
关键词
COUPLED ELECTRON-TRANSFER; CARBON-PASTE ELECTRODE; PALLADIUM NANOPARTICLES; GOLD NANOPARTICLES; VOLTAMMETRIC DETERMINATION; ELECTROCHEMICAL-BEHAVIOR; METAL NANOPARTICLES; CHEMICAL-SYNTHESIS; GLUCOSE BIOSENSOR; TRYPTOPHAN;
D O I
10.1039/c3dt53567c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We report on a bottom up approach for the synthesis of a Pd-polypyrrole nanocomposite material. The composite material was characterized by means of different techniques, such as UV-vis, IR, and Raman spectroscopy, which offered information about the chemical structure of the polymer, whereas electron microscopy images provided information regarding the morphology of the composite material and the distribution of the metal particles in the polymer matrix. During the synthesis of the nanocomposite, the Pd nanoparticles act as a catalyst for a model proton-coupled electron transfer reaction. The Pd-polypyrrole nanocomposite material was also used as a catalyst for the electro-catalytic detection of tryptophan, a precursor for some neurotransmitters.
引用
收藏
页码:6396 / 6405
页数:10
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