High sensitive luminescence metal-organic framework sensor for hydrogen sulfide in aqueous solution: A trial of novel turn-on mechanism

被引:66
作者
Cao, Yuan-Yuan [1 ,2 ]
Guo, Xiao-Feng [1 ,2 ]
Wang, Hong [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Key Lab Analyt Chem Biol & Med, Minist Educ, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Suzhou Inst, Suzhou 215123, Peoples R China
关键词
Fluorescent probe; Hydrogen sulfide; Sensor; Metal-organic framework; RATIOMETRIC FLUORESCENT-PROBE; GASEOUS SIGNALING MOLECULE; LIVING CELLS; H2S; DISEASE; NEUROMODULATOR; MITOCHONDRIA; CONSUMPTION; RECOGNITION; TISSUES;
D O I
10.1016/j.snb.2016.11.085
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Metal-organic framework (MOF) is a class of crystalline porous solid materials which could be designed as sensors for bioactive molecules. In this study, we illustrated a novel turn-on mechanism based on collapse of MOF structure for luminescence MOF sensors. Taking H2S as an analyte, we validated our mechanism using a specially selected MOF material Fe-III-MIL-88-NH2 for H2S sensing. The detection limit towards H2S is about 10 p,M, which is lower than the reported MOF sensors for H2S designing with other turn-on mechanism. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:8 / 13
页数:6
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