NIR J-Aggregates of Hydroazaheptacene Tetraimides

被引:113
作者
Cai, Kang
Xie, Jiajun
Zhao, Dahui [1 ]
机构
[1] Peking Univ, Coll Chem, Minist Educ, Beijing Natl Lab Mol Sci,Dept Appl Chem, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
PERYLENE BISIMIDE DYES; INFRARED ABSORBING DYES; LIGHT-EMITTING-DIODES; OPTICAL-PROPERTIES; FLUORESCENT DYES; MEROCYANINE DYES; RATIONAL DESIGN; SOLAR-CELLS; PI-STACKS; BAND;
D O I
10.1021/ja410265n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydroazaacene dicarboximide derivatives with red to NIR absorptions are designed and synthesized, which exhibit well-defined J-aggregation behaviors in both solution and thin films. The absorption and emission of an aggregate extend well into the NIR regime (lambda(max) = 902 nm), manifesting particularly narrow bandwidth (fwhm = 152 cm(-1)) and is nearly transparent in the visible region.
引用
收藏
页码:28 / 31
页数:4
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