Utilization of Common Ligands for the Ruthenium-Catalyzed Amination of Alcohols

被引：55
|
作者：
Baumann, Wolfgang [1 ]
Spannenberg, Anke [1 ]
Pfeffer, Jan [2 ]
Haas, Thomas [2 ]
Koeckritz, Angela [1 ]
Martin, Andreas [1 ]
Deutsch, Jens [1 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
[2] Evonik Ind AG, CREAVIS Technol & Innovat, D-45772 Marl, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 52期
关键词：
alcohols; amines; ammonia; homogeneous catalysis; ruthenium; PRIMARY AMINES; BORROWING HYDROGEN; SECONDARY ALCOHOLS; AMMONIA; ESTERS;
D O I：
10.1002/chem.201302774
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Simultaneous presence of bidentate phosphines with surprisingly simple structure and of the ligand triphenylphosphine were revealed as structural characteristics of new Ru catalysts for the selective conversion of primary and secondary alcohols and diols into their corresponding primary amines and diamines (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：17702 / 17706
页数：5
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