Synthesis and crystal structure of one-dimensional zinc(II) polymer constructed by salicylate and trans-1,2-bis(4-pyridyl)ethylene

被引：8
作者：
Jung, Eun Ju [1 ]
Lee, Uk [2 ]
Koo, Bon Kweon [1 ]
机构：
[1] Catholic Univ Daegu, Dept Chem, Gyongsan 712702, Gyeongbuk, South Korea
[2] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 05期
关键词：
Zn(II) complex; trans-1,2-Bis(4-pyridyl)ethylene; Salicylate; Crystal structure; COORDINATION POLYMER; MAGNETIC-PROPERTIES; COPPER(II) COMPLEXES; PYRIDINECARBOXYLATES; 4,4'-BIPYRIDINE; CARBOXYLATE; ADSORPTION; FRAMEWORKS; BINUCLEAR; NETWORKS;
D O I：
10.1016/j.ica.2008.08.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new zinc(II) compound, [Zn-2(Hsal)(4)(4,4'-bpe)(2)] center dot [Zn(Hsal)(2)(4,4'-bpe)(DMF)(H2O)] center dot CH3OH (1) (Hsal = salicylate and 4,4'-bpe = trans-1,2-bis(4-pyridyl)ethylene) has been synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The crystal structure consists of three independent moieties: [Zn-2(Hsal)(4)(4,4'-bpe)(2)], [Zn(Hsal)(2)(4,4'-bpe)(DMF)(H2O)], and non-coordinated CH3OH molecule. In the compound two independent moieties which are connected by 4,4'-bpe to form 1-D chains, respectively, are further expended to accomplish 2-D network through hydrogen-bonding interactions between non-coordinated methanol and coordinated water molecule or carboxylate oxygen atoms of Hsal ligands. (C) 2008 Elsevier B.V. All rights reserved.
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页码：1655 / 1659
页数：5
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