Two new polymorphs of trans-bis(hinokitiolato)copper(II)

被引：7
作者：
Arvanitis, GM
Berardini, ME
Ho, DM
机构：
[1] Coll New Jersey, Dept Chem, Ewing, NJ 08628 USA
[2] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S0108270104001957
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title complex [systematic name: trans-bis(3-isopropyl-7-oxocyclohepta-1,3,5-trienolato)copper(II)], [Cu(C10H11O2)(2)], is a substance possessing antimicrobial activity. The compound crystallizes in a number of polymorphic forms, the structures for two of which are reported here. Stacks of square-planar molecules exhibiting weak intermolecular copper-olefin pi interactions (not observed in earlier reports on this substance) are described. The molecules have crystallographically imposed inversion symmetry, with stacking and copper-olefin pi distances ranging from 3.226 (2) to 3.336 (1) Angstrom.
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页码：M126 / M128
页数：3
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