Recent Advances on Copper-Catalyzed C-C Bond Formation via C-H Functionalization

被引:9
作者
Almasalma, Ahmad A. [1 ]
Mejia, Esteban [1 ]
机构
[1] Leibniz Inst Catalysis, Albert Einstein Str 20, D-18059 Rostock, Germany
来源
SYNTHESIS-STUTTGART | 2020年 / 52卷 / 18期
关键词
copper; cross-dehydrogenative coupling; C-H derivatization; oxidants; photocatalysis; DEHYDROGENATIVE-COUPLING REACTION; CROSS; ACTIVATION; COMPLEXES; ARYLATION; METALS; ACCESS; ETHERS; GREEN;
D O I
10.1055/s-0040-1707815
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactions that form C-C bonds are at the heart of many important transformations, both in industry and in academia. From the myriad of catalytic approaches to achieve such transformations, those relying on C-H functionalization are gaining increasing interest due to their inherent sustainable nature. In this short review, we showcase the most recent advances in the field of C-C bond formation via C-H functionalization, but focusing only on those methodologies relying on copper catalysts. This coinage metal has gained increased popularity in recent years, not only because it is cheaper and more abundant than precious metals, but also thanks to its rich and versatile chemistry.
引用
收藏
页码:2613 / 2622
页数:10
相关论文
共 79 条
[21]   Oxidative C-C bond formation and C-N bond cleavage catalyzed by complexes of copper(i) with acridine based (E N E) pincers (E = S/Se), recyclable as a catalyst [J].
Gupta, Sonu ;
Dubey, Pooja ;
Singh, Ajai K. ;
Jain, Nidhi .
DALTON TRANSACTIONS, 2019, 48 (27) :10129-10137
[22]   Continuous-Flow TechnologyA Tool for the Safe Manufacturing of Active Pharmaceutical Ingredients [J].
Gutmann, Bernhard ;
Cantillo, David ;
Kappe, C. Oliver .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (23) :6688-6728
[23]  
Hessel Volker., 2008, Microreactors in Organic Synthesis and Catalysis, chapter Industrial Microreactor Process Development up to Production, P211
[24]   Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO) [J].
Himes, Richard A. ;
Karlin, Kenneth D. .
CURRENT OPINION IN CHEMICAL BIOLOGY, 2009, 13 (01) :119-131
[25]   The Use of Molecular Oxygen for Liquid Phase Aerobic Oxidations in Continuous Flow [J].
Hone, Christopher A. ;
Kappe, C. Oliver .
TOPICS IN CURRENT CHEMISTRY, 2019, 377 (01)
[26]   ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis [J].
Hossain, Asik ;
Bhattacharyya, Aditya ;
Reiser, Oliver .
SCIENCE, 2019, 364 (6439) :450-+
[27]   En Route to Intermolecular Cross-Dehydrogenative Coupling Reactions [J].
Huang, Chia-Yu ;
Kang, Hyotaik ;
Li, Jianbin ;
Li, Chao-Jun .
JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (20) :12705-12721
[28]   Copper-Catalyzed Dehydrogenative Cross-Coupling Reaction between Allylic C-H Bonds and α-C-H Bonds of Ketones or Aldehydes [J].
Huang, Xing-Fen ;
Salman, Muhammad ;
Huang, Zhi-Zhen .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (22) :6618-6621
[29]   Copper-Catalyzed Oxidative Dimerization of 2-Oxindoles under Base-Free Conditions [J].
Huang, Yi-Ling ;
Bao, Wen-Hui ;
Ying, Wei-Wei ;
Chen, Wei-Ting ;
Gao, Le-Han ;
Wang, Xin-Ye ;
Chen, Gan-Ping ;
Ge, Guo-Ping ;
Wei, Wen-Ting .
SYNLETT, 2018, 29 (11) :1485-1490
[30]   Double-Oxidative Dehydrogenative (DOD) [4+2]-Cyclization/Oxidative Aromatization Tandem Reaction of Glycine Derivatives with Ethylbenzenes [J].
Jiang, Wei ;
Wang, Yajun ;
Niu, Pengfei ;
Quan, Zhengjun ;
Su, Yingpeng ;
Huo, Congde .
ORGANIC LETTERS, 2018, 20 (15) :4649-4653