Catalytic hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to biofuel 2, 5-dimethylfuran

被引：67

作者：

Wang, Xiaofeng ^{[1
]}

Liang, Xinhua ^{[2
]}

Li, Jiaomin ^{[1
]}

Li, Qingbo ^{[1
]}

机构：

[1] Dalian Maritime Univ, Coll Environm Sci & Engn, Dalian 116026, Peoples R China

[2] Missouri Univ Sci & Technol, Dept Chem & Biochem Engn, Rolla, MO 65409 USA

来源：

APPLIED CATALYSIS A-GENERAL | 2019年 / 576卷

关键词：

5-Hydroxymethylfurfural (HMF); 2,5-Dimethylfuran (DMF); Hydrogenolysis; Metal catalyst; Biofuel; LIQUID FUEL 2,5-DIMETHYLFURAN; COPPER-NICKEL CATALYSTS; SELECTIVE HYDROGENATION; GAMMA-VALEROLACTONE; CARBON NANOTUBES; TRANSFER HYDROGENATION/HYDROGENOLYSIS; CHEMOSELECTIVE HYDROGENATION; BIMETALLIC NANOPARTICLES; EFFICIENT HYDROGENOLYSIS; METAL-CATALYSTS;

D O I：

10.1016/j.apcata.2019.03.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

2, 5-dimethylfuran (DMF), which is synthesized through catalytic hydrogenolysis of 5-hydroxymethylfurfural (HMF), is one of the most promising liquid biofuels for transportation because of its high energy density, high boiling point, and water insolubility. In recent years, studies of the hydrogenolysis of HMF to DMF have attracted increasing attention, with numerous novel catalytic systems and significant research achievements being reported as a result. Thus, in this review, we focus on hydrogenolysis of HMF into DMF through various catalytic systems, and systemically summarize the latest advances and progress on this reaction from the perspective of catalysts, including noble and non-noble metal-based catalysts. Moreover, the reaction mechanisms for different catalysts, the limitations and problems in current research, and potential research trends are discussed in this review.

引用

页码：85 / 95

页数：11

共 95 条

[91] Efficient Production of the Liquid Fuel 2,5-Dimethylfuran from 5-Hydroxymethylfurfural in the Absence of Acid Additive over Bimetallic PdAu Supported on Graphitized Carbon [J].

Zhang, Feng ;

Liu, Yunfei ;

Yuan, Fulong ;

Niu, Xiaoyu ;

Zhu, Yujun .

ENERGY & FUELS, 2017, 31 (06) :6364-6373

[92] Catalytic in-situ hydrogenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Cu-based catalysts with methanol as a hydrogen donor [J].

Zhang, Zihao ;

Wang, Changxue ;

Gou, Xin ;

Chen, Hao ;

Chen, Kequan ;

Lu, Xiuyang ;

Ouyang, Pingkai ;

Fu, Jie .

APPLIED CATALYSIS A-GENERAL, 2019, 570 :245-250

[93] Selective Hydrodeoxygenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over Ni Supported on Zirconium Phosphate Catalysts [J].

Zhu, Changhui ;

Liu, Qiying ;

Li, Dan ;

Wang, Haiyong ;

Zhang, Caihong ;

Cui, Chunhua ;

Chen, Lungang ;

Cai, Chiliu ;

Ma, Longlong .

ACS OMEGA, 2018, 3 (07) :7407-7417

[94] Efficient synthesis of 2,5-dihydroxymethylfuran and 2,5-dimethylfuran from 5-hydroxymethylfurfural using mineral-derived Cu catalysts as versatile catalysts [J].

Zhu, Yifeng ;

Kong, Xiao ;

Zheng, Hongyan ;

Ding, Guoqiang ;

Zhu, Yulei ;

Li, Yong-Wang .

CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (08) :4208-4217

[95] Efficient production of the liquid fuel 2,5-dimethylfuran from 5-hydroxymethylfurfural over Ru/Co3O4 catalyst [J].

Zu, Yanhong ;

Yang, Panpan ;

Wang, Jianjian ;

Liu, Xiaohui ;

Ren, Jiawen ;

Lu, Guanzhong ;

Wang, Yanqin .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 146 :244-248

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